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3D Printing of High Viscosity Reinforced Silicone Elastomers.
Rodriguez, Nicholas; Ruelas, Samantha; Forien, Jean-Baptiste; Dudukovic, Nikola; DeOtte, Josh; Rodriguez, Jennifer; Moran, Bryan; Lewicki, James P; Duoss, Eric B; Oakdale, James S.
Afiliación
  • Rodriguez N; Materials Engineering Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Ruelas S; Department of Mechanical Engineering, The University of Texas at Austin, 204 E. Dean Keeton Street, Austin, TX 78712, USA.
  • Forien JB; Materials Science Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Dudukovic N; Materials Science Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • DeOtte J; Materials Engineering Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Rodriguez J; Materials Engineering Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Moran B; Materials Science Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Lewicki JP; Materials Engineering Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Duoss EB; Materials Engineering Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
  • Oakdale JS; Materials Engineering Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550, USA.
Polymers (Basel) ; 13(14)2021 Jul 08.
Article en En | MEDLINE | ID: mdl-34300996
Recent advances in additive manufacturing, specifically direct ink writing (DIW) and ink-jetting, have enabled the production of elastomeric silicone parts with deterministic control over the structure, shape, and mechanical properties. These new technologies offer rapid prototyping advantages and find applications in various fields, including biomedical devices, prosthetics, metamaterials, and soft robotics. Stereolithography (SLA) is a complementary approach with the ability to print with finer features and potentially higher throughput. However, all high-performance silicone elastomers are composites of polysiloxane networks reinforced with particulate filler, and consequently, silicone resins tend to have high viscosities (gel- or paste-like), which complicates or completely inhibits the layer-by-layer recoating process central to most SLA technologies. Herein, the design and build of a digital light projection SLA printer suitable for handling high-viscosity resins is demonstrated. Further, a series of UV-curable silicone resins with thiol-ene crosslinking and reinforced by a combination of fumed silica and MQ resins are also described. The resulting silicone elastomers are shown to have tunable mechanical properties, with 100-350% elongation and ultimate tensile strength from 1 to 2.5 MPa. Three-dimensional printed features of 0.4 mm were achieved, and complexity is demonstrated by octet-truss lattices that display negative stiffness.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2021 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2021 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Suiza