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Physics of agarose fluid gels: Rheological properties and microstructure.
Ghebremedhin, Marta; Seiffert, Sebastian; Vilgis, Thomas A.
Afiliación
  • Ghebremedhin M; Max Planck Institute for Polymer Research, Department of Polymer Theory, Food Science and Statistical Physics of Soft Matter, Ackermannweg 10, 55128, Mainz, Germany.
  • Seiffert S; Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128, Mainz, Germany.
  • Vilgis TA; Max Planck Institute for Polymer Research, Department of Polymer Theory, Food Science and Statistical Physics of Soft Matter, Ackermannweg 10, 55128, Mainz, Germany.
Curr Res Food Sci ; 4: 436-448, 2021.
Article en En | MEDLINE | ID: mdl-34258588
Agarose, a strongly gelling polysaccharide, is a common ingredient used to optimize the viscoelastic properties of a multitude of food products. Through aggregation of double helices via hydrogen bonds while cooling under quiescent conditions it forms firm and brittle gels. However, this behavior can be altered by manipulating the processing conditions viz shear. For example, gelation under shear leads to microgel particles with large surface area, which in turn leads to completely different rheological properties and texture. Such fluid gels are shown to play an important role in texture modification of foods and beverages for dysphagia patients. In this study, different concentration of agarose fluid gel (0.5 % wt, 1 % wt and 2 % wt) were considered. Rheological measurements of the microgel particles showed an increase of storage and loss modulus with increasing concentration. However, 1 % wt fluid gel exhibited the lowest viscosity in the low shear range and the shortest LVE range. Furthermore, the effect on the microstructure and size of gel particles were also investigated by using light microscopy and particle size analysis. It was observed that as the concentration of agarose increased the particle size and unordered chains present at the particle surface decreases. Based on our results, we propose specific models suggesting the impact of the particle size, the concentration and the "hairy" projections on the rheological and tribological properties that could help in understanding the differences in characteristics of fluid gels.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Curr Res Food Sci Año: 2021 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Curr Res Food Sci Año: 2021 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Países Bajos