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An upper bound visualization of design trade-offs in adsorbent materials for gas separations: alkene/alkane adsorbents.
Elashkar, Ahmed H; Hedley, Gavin S; Qazvini, Omid T; Telfer, Shane G; Cowan, Matthew G.
Afiliación
  • Elashkar AH; MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemical and Process Engineering, University of Canterbury, Christchurch, 8140, New Zealand. matthew.cowan@canterbury.ac.nz.
  • Hedley GS; MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemical and Process Engineering, University of Canterbury, Christchurch, 8140, New Zealand. matthew.cowan@canterbury.ac.nz.
  • Qazvini OT; Department of Chemical Engineering and Analytical Science, The University of Manchester, Manchester M13 9PL, UK.
  • Telfer SG; MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Fundamental Sciences, Massey University, Palmerston North, New Zealand.
  • Cowan MG; MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemical and Process Engineering, University of Canterbury, Christchurch, 8140, New Zealand. matthew.cowan@canterbury.ac.nz.
Chem Commun (Camb) ; 57(57): 6950-6959, 2021 Jul 21.
Article en En | MEDLINE | ID: mdl-34159980
The last 20 years has seen an explosion in the number of publications investigating porous solids for gas adsorption and separation. The combination of external drivers such as anthropogenic climate change and industrial efficiency has been coupled with discovery of new materials such as synthetic zeolites, metal-organic frameworks, covalent organic frameworks, and non-porous adsorbents. Numerous reviews catalogue these materials and their properties. However, the field lacks a unifying resource to visually compare and analyse materials properties with regard to their utility as a scientific advance and potential for industrial use. In the related field of membrane science, the 'Robeson upper bound' empirically describes the trade-off between gas permeability and selectivity and has become a ubiquitous tool for comparing membrane materials. In this article, we propose upper and lower bounds that empirically correlate the trade-offs encountered when designing adsorbent materials for gas separation, specifically: capacity, selectivity, and heat of adsorption. We apply bound visualizations to adsorbents studied for light alkene/alkane separations and highlight their use in identifying candidate materials for examination within process models and for guiding insights to the most effective materials design strategies. Furthermore, we note the limitations of upper and lower bound visualizations and provide links to a database resource for researchers to produce and download bound visualization plots. We anticipate that introducing bound visualizations to the field of adsorbents for gas separations will allow researchers to provide context for the importance of new materials discoveries, understand trade-offs in adsorbent design, and connect process engineers with candidate materials.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: Nueva Zelanda Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: Nueva Zelanda Pais de publicación: Reino Unido