Your browser doesn't support javascript.
loading
Through-Space Charge Transfer in Copper Coordination Networks with Copper-Halide Guest Anions.
Ohtsu, Hiroyoshi; Okuyama, Marie; Nakajima, Takeshi; Iwamura, Munetaka; Nozaki, Koichi; Hashizume, Daisuke; Kawano, Masaki.
Afiliación
  • Ohtsu H; Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo, 152-8550, Japan.
  • Okuyama M; RIKEN Center for Emergent Matter Science (CEMS), 2-1, Hirosawa, Wako-shi, Saitama 351-0198, Japan.
  • Nakajima T; Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo, 152-8550, Japan.
  • Iwamura M; Graduate School of Science and Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
  • Nozaki K; Graduate School of Science and Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
  • Hashizume D; Graduate School of Science and Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
  • Kawano M; RIKEN Center for Emergent Matter Science (CEMS), 2-1, Hirosawa, Wako-shi, Saitama 351-0198, Japan.
Inorg Chem ; 60(13): 9273-9277, 2021 Jul 05.
Article en En | MEDLINE | ID: mdl-34128658
We prepared coordination networks that show relatively strong emission with through-space charge-transfer (TSCT) transitions. Thermolysis of a kinetically assembled network with Cu2Br2 dimer connectors, which was assembled from a CuBr cluster and the Td ligand 4-4-tetrapyridyltetraphenylmethane (4-TPPM), generated a highly luminescent network composed of Cu+ connectors and 4-TPPM linkers with CuBr2- guests. We clarified that the electronic transitions in this network include TSCT in addition to the typical metal-ligand charge transfer (MLCT) observed in conventional Cu complexes.
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2021 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2021 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos