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A luminescent view of the clickable assembly of LnF3 nanoclusters.
Zhou, Jie; Wei, Yang; Pan, Yue; Wang, Yue; Yuan, Ze; Zhang, Fan; Song, Hao; Yue, Jingyi; Su, Haiquan; Xie, Xiaoji; Huang, Ling.
Afiliación
  • Zhou J; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Wei Y; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Pan Y; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Wang Y; School of Chemistry and Chemical Engineering, Inner Mongolia University, 235 West Daxue Road, Hohhot, China.
  • Yuan Z; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Zhang F; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Song H; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Yue J; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Su H; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China.
  • Xie X; School of Chemistry and Chemical Engineering, Inner Mongolia University, 235 West Daxue Road, Hohhot, China.
  • Huang L; Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing, China. iamxjxie@njtech.edu.cn.
Nat Commun ; 12(1): 2948, 2021 05 19.
Article en En | MEDLINE | ID: mdl-34011957
Nanoclusters (NCs) bridge the gap between atoms and nanomaterials in not only dimension but also physicochemical properties. Precise chemical and structural control, as well as clear understanding of formation mechanisms, have been important to fabricate NCs with high performance in optoelectronics, catalysis, nanoalloys, and energy conversion and harvesting. Herein, taking advantage of the close chemical properties of Ln3+ (Ln = Eu, Nd, Sm, Gd, etc.) and Gd3+-Eu3+ energy transfer ion-pair, we report a clickable LnF3 nanoparticle assembly strategy allowing reliable fabrication of diversely structured NCs, including single-component, dimeric, core-shelled/core-shell-shelled, and reversely core-shelled/core-shell-shelled, particularly with synergized optical functionalities. Moreover, the purposely-embedded dual luminescent probes offer great superiority for in situ and precise tracking of tiny structural variations and energy transfer pathways within complex nanoarchitectures.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nat Commun Asunto de la revista: BIOLOGIA / CIENCIA Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nat Commun Asunto de la revista: BIOLOGIA / CIENCIA Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido