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Ligand-engineered bandgap stability in mixed-halide perovskite LEDs.
Hassan, Yasser; Park, Jong Hyun; Crawford, Michael L; Sadhanala, Aditya; Lee, Jeongjae; Sadighian, James C; Mosconi, Edoardo; Shivanna, Ravichandran; Radicchi, Eros; Jeong, Mingyu; Yang, Changduk; Choi, Hyosung; Park, Sung Heum; Song, Myoung Hoon; De Angelis, Filippo; Wong, Cathy Y; Friend, Richard H; Lee, Bo Ram; Snaith, Henry J.
Afiliación
  • Hassan Y; Clarendon Laboratory, Department of Physics, University of Oxford, Oxford, UK. yasserhassan8085@gmail.com.
  • Park JH; Department of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, Republic of Korea.
  • Crawford ML; Department of Chemistry and Biochemistry, University of Oregon, Eugene, OR, USA.
  • Sadhanala A; Clarendon Laboratory, Department of Physics, University of Oxford, Oxford, UK.
  • Lee J; Centre for Nano Science and Engineering, Indian Institute of Science, Bangalore, India.
  • Sadighian JC; Cavendish Laboratory, University of Cambridge, Cambridge, UK.
  • Mosconi E; School of Earth and Environmental Sciences, Seoul National University, Seoul, Republic of Korea.
  • Shivanna R; Department of Chemistry and Biochemistry, University of Oregon, Eugene, OR, USA.
  • Radicchi E; Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche 'Giulio Natta' (CNR-SCITEC), Perugia, Italy.
  • Jeong M; Cavendish Laboratory, University of Cambridge, Cambridge, UK.
  • Yang C; Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche 'Giulio Natta' (CNR-SCITEC), Perugia, Italy.
  • Choi H; Department of Chemistry, Biology and Biotechnology, University of Perugia, Perugia, Italy.
  • Park SH; Department of Energy Engineering, School of Energy and Chemical Engineering, Perovtronics Research Center, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), Ulsan, Republic of Korea.
  • Song MH; Department of Energy Engineering, School of Energy and Chemical Engineering, Perovtronics Research Center, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), Ulsan, Republic of Korea.
  • De Angelis F; Department of Chemistry, Research Institute for Convergence of Basic Sciences, Research Institute for Natural Sciences, Hanyang University, Seoul, Republic of Korea.
  • Wong CY; Department of Physics, Pukyong National University, Busan, Republic of Korea.
  • Friend RH; Department of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, Republic of Korea.
  • Lee BR; Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche 'Giulio Natta' (CNR-SCITEC), Perugia, Italy.
  • Snaith HJ; Department of Chemistry, Biology and Biotechnology, University of Perugia, Perugia, Italy.
Nature ; 591(7848): 72-77, 2021 03.
Article en En | MEDLINE | ID: mdl-33658694
Lead halide perovskites are promising semiconductors for light-emitting applications because they exhibit bright, bandgap-tunable luminescence with high colour purity1,2. Photoluminescence quantum yields close to unity have been achieved for perovskite nanocrystals across a broad range of emission colours, and light-emitting diodes with external quantum efficiencies exceeding 20 per cent-approaching those of commercial organic light-emitting diodes-have been demonstrated in both the infrared and the green emission channels1,3,4. However, owing to the formation of lower-bandgap iodide-rich domains, efficient and colour-stable red electroluminescence from mixed-halide perovskites has not yet been realized5,6. Here we report the treatment of mixed-halide perovskite nanocrystals with multidentate ligands to suppress halide segregation under electroluminescent operation. We demonstrate colour-stable, red emission centred at 620 nanometres, with an electroluminescence external quantum efficiency of 20.3 per cent. We show that a key function of the ligand treatment is to 'clean' the nanocrystal surface through the removal of lead atoms. Density functional theory calculations reveal that the binding between the ligands and the nanocrystal surface suppresses the formation of iodine Frenkel defects, which in turn inhibits halide segregation. Our work exemplifies how the functionality of metal halide perovskites is extremely sensitive to the nature of the (nano)crystalline surface and presents a route through which to control the formation and migration of surface defects. This is critical to achieve bandgap stability for light emission and could also have a broader impact on other optoelectronic applications-such as photovoltaics-for which bandgap stability is required.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nature Año: 2021 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nature Año: 2021 Tipo del documento: Article Pais de publicación: Reino Unido