Your browser doesn't support javascript.
loading
Zeolite-Stabilized Di- and Tetranuclear Molybdenum Sulfide Clusters Form Stable Catalytic Hydrogenation Sites.
Weindl, Roland; Khare, Rachit; Kovarik, Libor; Jentys, Andreas; Reuter, Karsten; Shi, Hui; Lercher, Johannes A.
Afiliación
  • Weindl R; Department of Chemistry and Catalysis Research Center, Technical University of Munich, 85747, Garching, Germany.
  • Khare R; Department of Chemistry and Catalysis Research Center, Technical University of Munich, 85747, Garching, Germany.
  • Kovarik L; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
  • Jentys A; Department of Chemistry and Catalysis Research Center, Technical University of Munich, 85747, Garching, Germany.
  • Reuter K; Department of Chemistry and Catalysis Research Center, Technical University of Munich, 85747, Garching, Germany.
  • Shi H; Fritz Haber Institute of the Max Planck Society, 14195, Berlin, Germany.
  • Lercher JA; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, China.
Angew Chem Int Ed Engl ; 60(17): 9301-9305, 2021 Apr 19.
Article en En | MEDLINE | ID: mdl-33576131
Supercages of faujasite (FAU)-type zeolites serve as a robust scaffold for stabilizing dinuclear (Mo2 S4 ) and tetranuclear (Mo4 S4 ) molybdenum sulfide clusters. The FAU-encaged Mo4 S4 clusters have a distorted cubane structure similar to the FeMo-cofactor in nitrogenase. Both clusters possess unpaired electrons on Mo atoms. Additionally, they show identical catalytic activity per sulfide cluster. Their catalytic activity is stable (>150 h) for ethene hydrogenation, while layered MoS2 structures deactivate significantly under the same reaction conditions.
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2021 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2021 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania