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Synthesis, Characterization and Biological Evaluation of Indole-Pyrazole Amalgamated α-Cyano Substituted Chalcones.
Bhale, Pravin S; Shringare, Sadanand N; Khade, Amol B; Chavan, Hemant V.
Afiliación
  • Bhale PS; Department of Chemistry, Yeshwantrao Chavan Mahavidyalaya, Tuljapur, Dist-Osmanabad-413 601, Maharashtra, India.
  • Shringare SN; School of Chemical Sciences, Solapur University Solapur-413 255, Maharashtra, India.
  • Khade AB; Department of Quality Assurance, Indira Institute of Pharmacy, Devrukh, Dist-Ratnagiri-415 804, Maharashtra, India.
  • Chavan HV; Department of Chemistry, A.S.P. College, Devrukh, Dist-Ratnagiri- 415 804, Maharashtra, India.
Anticancer Agents Med Chem ; 21(16): 2216-2223, 2021 10 28.
Article en En | MEDLINE | ID: mdl-33563183
BACKGROUND: Indole and pyrazole constitute a major class of biologically active scaffolds. The amalgamation of two or more pharmacophores would generate novel molecular templates that are likely to unveil remarkable biological properties. OBJECTIVE: An efficient and high yielding synthesis of indole-pyrazole integrated α-cyano substituted chalcones and their in vitro anti-breast cancer and antioxidant evaluation. METHODS: The synthesis of a series of indole-pyrazole amalgamated α-cyano substituted chalcones (6a-o) was achieved by reacting substituted 3-cyanoacetyl indole 2 with substituted pyrazole aldehyde 5 in the presence of piperidine. All the newly synthesized compounds have been characterized by IR, 1H NMR and HRMS spectroscopy. RESULTS: Anti-breast cancer evaluation of the synthesized compounds in vitro against MCF-7 cell line revealed high anti-breast cancer activities. Amongst the compounds screened 6f, 6g, 6h, 6c, 6d, 6e, 6i and 6k unveiled excellent activity against breast carcinoma (GI50 <0.1µM) as good as adriamycin (GI50 <0.1µM). The compounds were also screened against the normal Vero monkey cell line and the results demonstrated more selectivity against MCF-7. On the other hand, compounds 6b, 6c, 6d, 6h and 6i have shown moderate DPPH and NO radical scavenging activity. CONCLUSION: Most of the synthesized compounds exhibited significant antitumor activities. These results further support its safety margin by studying the activity on normal Vero monkey cell line. These results acclaim the possible use of these compounds for the design and development of potent anti-breast cancer agents.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirazoles / Chalconas / Indoles / Antineoplásicos / Antioxidantes Límite: Animals / Humans Idioma: En Revista: Anticancer Agents Med Chem Asunto de la revista: ANTINEOPLASICOS / QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: India Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirazoles / Chalconas / Indoles / Antineoplásicos / Antioxidantes Límite: Animals / Humans Idioma: En Revista: Anticancer Agents Med Chem Asunto de la revista: ANTINEOPLASICOS / QUIMICA Año: 2021 Tipo del documento: Article País de afiliación: India Pais de publicación: Países Bajos