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Transparent Molecular Adhesive Enabling Mechanically Stable ITO Thin Films.
Bok, Shingyu; Seok, Hae-Jun; Kim, Yun Ah; Park, Jin-Hyeok; Kim, Jihyun; Kang, Joohoon; Kim, Han-Ki; Lim, Byungkwon.
Afiliación
  • Bok S; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Seok HJ; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Kim YA; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Park JH; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Kim J; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Kang J; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Kim HK; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
  • Lim B; School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
ACS Appl Mater Interfaces ; 13(2): 3463-3470, 2021 Jan 20.
Article en En | MEDLINE | ID: mdl-33416317
With rapid advances in flexible electronics, transparent conductive electrodes (TCEs) have also been significantly developed as alternatives to the conventional indium tin oxide (ITO)-based material systems that exhibit low mechanical flexibility. Nanomaterial-based alternating materials, such as graphene, nanowire, and nanomesh, exhibit remarkable properties for TCE-based applications, such as high electrical conductivity, high optical transparency, and high mechanical stability. However, these nanomaterial-based systems lack scalability, which is a key requirement for practical applications, and exhibit a size-dependent property variation and inhomogeneous surface uniformity that limit reliable properties over a large area. Here, we exploited a conventional ITO-based material platform; however, we incorporated a transparent molecular adhesive, 4-aminopyridine (4-AP), to improve mechanical flexibility. While the presence of 4-AP barely affected optical transmittance and sheet resistance, it improved interfacial adhesion between the substrate and ITO as well as formed a wavy surface, which could improve the mechanical flexibility. Under various mechanical tests, ITO/4-AP/poly(ethylene terephthalate) (PET) exhibited remarkably improved mechanical flexibility as compared with that of ITO/PET. Furthermore, ITO/4-AP/PET was utilized for a flexible Joule heater application having spatial uniformity of heat generation, voltage-dependent temperature control, and mechanical flexibility under repeated bending tests. This molecular adhesive could overcome the current limitations of material systems for flexible electronics.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2021 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2021 Tipo del documento: Article Pais de publicación: Estados Unidos