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Antimicrobial, Anticancer and Multidrug-Resistant Reversing Activity of Novel Oxygen-, Sulfur- and Selenoflavones and Bioisosteric Analogues.
Marc, Malgorzata Anna; Kincses, Annamária; Rácz, Bálint; Nasim, Muhammad Jawad; Sarfraz, Muhammad; Lázaro-Milla, Carlos; Domínguez-Álvarez, Enrique; Jacob, Claus; Spengler, Gabriella; Almendros, Pedro.
Afiliación
  • Marc MA; Department of Medical Microbiology and Immunobiology, University of Szeged, H-6720 Szeged, Hungary.
  • Kincses A; Department of Medical Microbiology and Immunobiology, University of Szeged, H-6720 Szeged, Hungary.
  • Rácz B; Department of Medical Microbiology and Immunobiology, University of Szeged, H-6720 Szeged, Hungary.
  • Nasim MJ; Division of Bioorganic Chemistry, School of Pharmacy, Saarland University, D-66123 Saarbruecken, Germany.
  • Sarfraz M; Division of Bioorganic Chemistry, School of Pharmacy, Saarland University, D-66123 Saarbruecken, Germany.
  • Lázaro-Milla C; Grupo de Lactamas y Heterociclos Bioactivos, Unidad Asociada al CSIC, Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, E-28040 Madrid, Spain.
  • Domínguez-Álvarez E; Instituto de Química Orgánica General IQOG-CSIC, Consejo Superior de Investigaciones Científicas, Juan de la Cierva 3, 28006 Madrid, Spain.
  • Jacob C; Division of Bioorganic Chemistry, School of Pharmacy, Saarland University, D-66123 Saarbruecken, Germany.
  • Spengler G; Department of Medical Microbiology and Immunobiology, University of Szeged, H-6720 Szeged, Hungary.
  • Almendros P; Instituto de Química Orgánica General IQOG-CSIC, Consejo Superior de Investigaciones Científicas, Juan de la Cierva 3, 28006 Madrid, Spain.
Pharmaceuticals (Basel) ; 13(12)2020 Dec 11.
Article en En | MEDLINE | ID: mdl-33322409
Multidrug resistance of cancer cells to cytotoxic drugs still remains a major obstacle to the success of chemotherapy in cancer treatment. The development of new drug candidates which may serve as P-glycoprotein (P-gp) efflux pump inhibitors is a promising strategy. Selenium analogues of natural products, such as flavonoids, offer an interesting motif from the perspective of drug design. Herein, we report the biological evaluation of novel hybrid compounds, bearing both the flavone core (compounds 1-3) or a bioisosteric analogue core (compounds 4-6) and the triflyl functional group against Gram-positive and Gram-negative bacteria, yeasts, nematodes, and human colonic adenocarcinoma cells. Results show that these flavones and analogues of flavones inhibited the activity of multidrug resistance (MDR) efflux pump ABCB1 (P-glycoprotein, P-gp). Moreover, the results of the rhodamine 123 accumulation assay demonstrated a dose-dependent inhibition of the abovementioned efflux pump. Three compounds (4, 5, and 6) exhibited potent inhibitory activity, much stronger than the positive control, verapamil. Thus, these chalcogen bioisosteric analogues of flavones become an interesting class of compounds which could be considered as P-gp efflux pump inhibitors in the therapy of MDR cancer. Moreover, all the compounds served as promising adjuvants in the cancer treatment, since they exhibited the P-gp efflux pump modulating activity.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Pharmaceuticals (Basel) Año: 2020 Tipo del documento: Article País de afiliación: Hungria Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Pharmaceuticals (Basel) Año: 2020 Tipo del documento: Article País de afiliación: Hungria Pais de publicación: Suiza