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Enhancing and Tuning the Nonlinear Optical Response and Wavelength-Agile Strong Optical Limiting Action of N-octylamine Modified Fluorographenes.
Stathis, Aristeidis; Stavrou, Michalis; Papadakis, Ioannis; Obratzov, Ievgen; Couris, Stelios.
Afiliación
  • Stathis A; Department of Physics, University of Patras, 26504 Patras, Greece.
  • Stavrou M; Institute of Chemical Engineering Sciences (ICE-HT), Foundation for Research and Technology-Hellas (FORTH), P.O. Box 1414, 26504 Patras, Greece.
  • Papadakis I; Department of Physics, University of Patras, 26504 Patras, Greece.
  • Obratzov I; Institute of Chemical Engineering Sciences (ICE-HT), Foundation for Research and Technology-Hellas (FORTH), P.O. Box 1414, 26504 Patras, Greece.
  • Couris S; Department of Physics, University of Patras, 26504 Patras, Greece.
Nanomaterials (Basel) ; 10(11)2020 Nov 23.
Article en En | MEDLINE | ID: mdl-33238499
Fluorographene has been recently shown to be a suitable platform for synthesizing numerous graphene derivatives with desired properties. In that respect, N-octylamine-modified fluorographenes with variable degrees of functionalization are studied and their nonlinear optical properties are assessed using 4 ns pulses. A very strong enhancement of the nonlinear optical response and a very efficient optical limiting action are observed, being strongly dependent on the degree of functionalization of fluorographene. The observed enhanced response is attributed to the increasing number of defects because of the incorporation of N-heteroatoms in the graphitic network upon functionalization with N-octylamine. The present work paves the way for the controlled covalent functionalization of graphene enabling a scalable access to a wide portfolio of graphene derivatives with custom-tailored properties.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomaterials (Basel) Año: 2020 Tipo del documento: Article País de afiliación: Grecia Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomaterials (Basel) Año: 2020 Tipo del documento: Article País de afiliación: Grecia Pais de publicación: Suiza