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White-Light-Emitting AIE/Eu3+-Doped Ion Gel with Multistimuli-Responsive Properties.
Tang, Zhehao; Lyu, Xiaolin; Luo, Longfei; Shen, Zhihao; Fan, Xing-He.
Afiliación
  • Tang Z; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
  • Lyu X; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
  • Luo L; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
  • Shen Z; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
  • Fan XH; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
ACS Appl Mater Interfaces ; 12(40): 45420-45428, 2020 Oct 07.
Article en En | MEDLINE | ID: mdl-32966044
A white-light-emitting ion gel composed of a poly[(2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene-b-ethylene glycol-b-(2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene] aggregation-induced emission (AIE) network and a poly([2,2':6',2″-terpyridin]-4'-yl methacrylate-co-methyl methacrylate) Eu3+-doped network was fabricated via a solution mixing process. This ion gel exhibits special multistimuli-responsive properties, and it can change its luminescent color by changing pH, temperature, or the solvent. The unique color-changing property is attributed to the different luminescent mechanisms of the AIE/Eu3+-doped polymer networks. The former is affected by changes in its aggregation state, while the latter is controlled by the dynamic metal-ligand cross-linking bonds. Furthermore, owing to the interpenetrating networks formed by the two polymers, the hybrid gel has both good mechanical strength and flexibility. It may be used in the fields of sensors, probes, and light-emitting materials.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2020 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2020 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos