Your browser doesn't support javascript.
loading
Dy3+ White Light Emission Can Be Finely Controlled by Tuning the First Coordination Sphere of Ga3+/Dy3+ Metallacrown Complexes.
Eliseeva, Svetlana V; Salerno, Elvin V; Lopez Bermudez, Beatriz A; Petoud, Stéphane; Pecoraro, Vincent L.
Afiliación
  • Eliseeva SV; Centre de Biophysique Moléculaire, CNRS UPR 4301, F-45071 Orléans, Cedex 2, France.
  • Salerno EV; Department of Chemistry, Willard H. Dow Laboratories, University of Michigan, Ann Arbor, Michigan 48109, United States.
  • Lopez Bermudez BA; Department of Chemistry, Willard H. Dow Laboratories, University of Michigan, Ann Arbor, Michigan 48109, United States.
  • Petoud S; Centre de Biophysique Moléculaire, CNRS UPR 4301, F-45071 Orléans, Cedex 2, France.
  • Pecoraro VL; Department of Chemistry, Willard H. Dow Laboratories, University of Michigan, Ann Arbor, Michigan 48109, United States.
J Am Chem Soc ; 142(38): 16173-16176, 2020 Sep 23.
Article en En | MEDLINE | ID: mdl-32962349
Single lanthanide(III) ion white light emission is in high demand since it provides the advantage of requiring only one chromophore for the control of the color. Herein, a series of Ga3+/Dy3+ metallacrowns (MCs) is presented, demonstrating outstanding white light colorimetric properties with CIE chromaticity coordinates of (0.309, 0.334) and correlated color temperature (CCT) equal to 6670 K for the MC emitting the closest to the standard white color. Experimental data reveal that the CIE coordinates within the studied series of MCs are controlled mainly by the Dy3+-centered emission rather than by the ligand-centered bands, implying that Dy3+ can be tuned as a single ionic white light emitter by a simple modification of the coordination environment.
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2020 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2020 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Estados Unidos