Predicting Properties of Iron(III) TAML Activators of Peroxides from Their III/IV and IV/V Reduction Potentials or a Lost Battle to Peroxidase.

Somasundar, Yogesh; Shen, Longzhu Q; Hoane, Alexis G; Kaaret, Evan Z; Warner, Genoa R; Ryabov, Alexander D; Collins, Terrence J

Somasundar, Yogesh; Shen, Longzhu Q; Hoane, Alexis G; Kaaret, Evan Z; Warner, Genoa R; Ryabov, Alexander D; Collins, Terrence J.

Afiliación

Somasundar Y; Institute for Green Science, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, PA, 15213, USA.
Shen LQ; University of Cambridge, Downing Street, Cambridge, CB2 3EJ, UK.
Hoane AG; Institute for Green Science, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, PA, 15213, USA.
Kaaret EZ; Institute for Green Science, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, PA, 15213, USA.
Warner GR; Institute for Green Science, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, PA, 15213, USA.
Ryabov AD; Present address: Department of Comparative Biosciences, University of Illinois, 2001 S. Lincoln Avenue, Urbana, IL 61802, USA.
Collins TJ; Institute for Green Science, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, PA, 15213, USA.

Chemistry ; 26(64): 14738-14744, 2020 Nov 17.

Article en En | MEDLINE | ID: mdl-32886381

Asunto(s)

Hierro; Peroxidasas/química; Peróxidos; Peróxido de Hidrógeno; Oxidación-Reducción

Palabras clave

electrochemistry; kinetics; linear free energy relationship (LFER); oxidation; redox potential

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Peroxidasas / Peróxidos / Hierro Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania

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