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Removal and toxicity evaluation of a diverse group of drugs from water by a cyclodextrin polymer/pulsed light system.
Gómez-Morte, T; Gómez-López, V M; Lucas-Abellán, C; Martínez-Alcalá, I; Ayuso, M; Martínez-López, S; Montemurro, N; Pérez, S; Barceló, D; Fini, P; Cosma, P; Cerón-Carrasco, J P; Fortea, M I; Núñez-Delicado, E; Gabaldón, J A.
Afiliación
  • Gómez-Morte T; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain.
  • Gómez-López VM; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain.
  • Lucas-Abellán C; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain.
  • Martínez-Alcalá I; Department of Civil Engineering, San Antonio Catholic University of Murcia (UCAM), Av. de los Jerónimos, 135, 30107, Guadalupe, Murcia, Spain.
  • Ayuso M; Departamento de Medio Ambiente, Centro Tecnológico Nacional de la Conserva y Alimentación, Calle Concordia, s/n, 30500, Molina de Segura, Murcia, Spain.
  • Martínez-López S; Departamento de Medio Ambiente, Centro Tecnológico Nacional de la Conserva y Alimentación, Calle Concordia, s/n, 30500, Molina de Segura, Murcia, Spain.
  • Montemurro N; ENFOCHEM, Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Jordi Girona 18-26, E-08034 Barcelona, Spain.
  • Pérez S; ENFOCHEM, Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Jordi Girona 18-26, E-08034 Barcelona, Spain.
  • Barceló D; ENFOCHEM, Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Jordi Girona 18-26, E-08034 Barcelona, Spain.
  • Fini P; Consiglio Nazionale delle Ricerche CNR-IPCF, UOS Bari, Via Orabona, 4, 70126 Bari, Italy.
  • Cosma P; Università degli Studi "Aldo Moro'' di Bari, Dip. Chimica, Via Orabona, 4, 70126 Bari, Italy.
  • Cerón-Carrasco JP; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain.
  • Fortea MI; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain.
  • Núñez-Delicado E; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain.
  • Gabaldón JA; Molecular Recognition and Encapsulation Research Group (REM), Health Sciences Department, Universidad Católica de Murcia (UCAM), Campus de los Jerónimos 135, Guadalupe, 30107, Spain. Electronic address: jagabaldon@ucam.edu.
J Hazard Mater ; 402: 123504, 2021 01 15.
Article en En | MEDLINE | ID: mdl-32717543
The presence of pharmaceutical compounds (PhCs) in the effluents of wastewater treatment plants (WWTPs) is an ecological concern. The issue could be alleviated by trapping those substances by cyclodextrin (CD) polymers or photolyzing them by pulsed light (PL). Consequently, a sequential CD polymer/PL system was tested for the removal of PhCs. Firstly, a survey detected the presence of recurrent PhCs in the effluents of local WWTPs. Then, pure water was spiked with 21 PhCs, 100 µg/L each one. The three-dimensional network provides amphiphilic features to the CD polymer that reduced the pollutant concentration by 77 %. Sorption involves a plead of physical and chemical mechanisms hindering the establishment of a general removal model for all compounds. The performed simulations hint that the retention capacity mainly correlates with the computed binding energies, so that theoretical models are revealed as valuable tools for further improvements. The complementary action of PL rose the elimination to 91 %. The polymer can be reused at least 10 times for ibuprofen (model compound) removal, and was able to eliminate the ecotoxicity of an ibuprofen solution. Therefore, this novel sequential CD polymer/PL process seems to be an efficient alternative to eliminate PhCs from wastewater.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Preparaciones Farmacéuticas / Ciclodextrinas Idioma: En Revista: J Hazard Mater Asunto de la revista: SAUDE AMBIENTAL Año: 2021 Tipo del documento: Article País de afiliación: España Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Preparaciones Farmacéuticas / Ciclodextrinas Idioma: En Revista: J Hazard Mater Asunto de la revista: SAUDE AMBIENTAL Año: 2021 Tipo del documento: Article País de afiliación: España Pais de publicación: Países Bajos