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Advances in Decarboxylative Palladium-Catalyzed Reactions of Propargyl Electrophiles.
O'Broin, Calvin Q; Guiry, Patrick J.
Afiliación
  • O'Broin CQ; Centre for Synthesis and Chemical Biology, School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
  • Guiry PJ; Centre for Synthesis and Chemical Biology, School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
J Org Chem ; 85(16): 10321-10333, 2020 08 21.
Article en En | MEDLINE | ID: mdl-32706581
The propargyl electrophile has proven to be a versatile reactant when coupled with palladium catalysis. Its versatility is owed to the several reaction pathways that the palladium-propargyl intermediate can proceed by, and the outcome can be predictably controlled by varying several factors. The tunable nature of the propargyl electrophile along with its versatility are detailed herein. The initial reports for each of the pathways are highlighted along with a discussion of more recent developments in the field.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: J Org Chem Año: 2020 Tipo del documento: Article País de afiliación: Irlanda Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: J Org Chem Año: 2020 Tipo del documento: Article País de afiliación: Irlanda Pais de publicación: Estados Unidos