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Laser-induced fluorescence detector with a fiber-coupled micro GRIN lens for capillary electrophoresis.
Appl Opt ; 59(16): 4849-4855, 2020 Jun 01.
Article en En | MEDLINE | ID: mdl-32543481
Capillary electrophoresis coupled with sheath-flow laser-induced fluorescence (LIF) detection has been shown to offer outstanding sensitivity for chemical and biochemical analysis. However, a major drawback remains with the complexity of the optical configuration traditionally employed. Here we present a simplified confocal optics based on fiber optics and micro gradient-index (GRIN) lenses for modular optical design in capillary electrophoresis with laser-induced fluorescence. We demonstrate the use of the optical system with a sheath-flow cuvette as the laser-induced fluorescence detector for capillary electrophoresis. The system's performance was established with concentration detection limits of 8±2pM and mass detection limits of 57 zeptomole for a standard sodium fluorescein sample.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Appl Opt Año: 2020 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Appl Opt Año: 2020 Tipo del documento: Article Pais de publicación: Estados Unidos