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Nickel-catalyzed allyl-allyl coupling reactions between 1,3-dienes and allylboronates.
Ji, Ding-Wei; He, Gu-Cheng; Zhang, Wei-Song; Zhao, Chao-Yang; Hu, Yan-Cheng; Chen, Qing-An.
Afiliación
  • Ji DW; Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China. qachen@dicp.ac.cn.
Chem Commun (Camb) ; 56(54): 7431-7434, 2020 Jul 11.
Article en En | MEDLINE | ID: mdl-32490858
A regiospecific allyl-allyl coupling reaction between 1,3-dienes and allylboronates has been demonstrated under nickel catalysis. Salient features of this method include the earth-abundant metal catalyst, excellent regioselectivity and good functional group tolerance. Notably, even congested allyl substrates can also be applied to this protocol, thus allowing for the rapid preparation of a series of valuable 1,5-dienes.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article Pais de publicación: Reino Unido