FeMoO<sub>4</sub> nanorods for efficient ambient electrochemical nitrogen reduction.

Wu, Jie; Wang, ZhongXu; Li, Siwei; Niu, Siqi; Zhang, Yuanyuan; Hu, Jing; Zhao, Jingxiang; Xu, Ping

FeMoO₄ nanorods for efficient ambient electrochemical nitrogen reduction.

Wu, Jie; Wang, ZhongXu; Li, Siwei; Niu, Siqi; Zhang, Yuanyuan; Hu, Jing; Zhao, Jingxiang; Xu, Ping.

Afiliación

Wu J; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China. pxu@hit.edu.cn swli@hit.edu.cn.

Chem Commun (Camb) ; 56(50): 6834-6837, 2020 Jun 25.

Article en En | MEDLINE | ID: mdl-32432254

RESUMEN

Herein, FeMoO4 nanorods are explored as an efficient electrocatalyst for nitrogen reduction reaction (NRR) in 0.1 M Na2SO4 solution, with an NH3 yield rate of 17.51 µg h-1 mg-1 and a high faradaic efficiency (FE) of 10.53%. Density functional theory (DFT) calculations reveal that surface Fe atoms are the active centers for NRR via an alternating mechanism.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article Pais de publicación: Reino Unido

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