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Dual-Localized Enzymatic Components Constitute the Fatty Acid Synthase Systems in Mitochondria and Plastids.
Guan, Xin; Okazaki, Yozo; Zhang, Rwisdom; Saito, Kazuki; Nikolau, Basil J.
Afiliación
  • Guan X; Roy J. Carver Department of Biochemistry, Biophysics, and Molecular Biology, Iowa State University, Ames, Iowa 50011.
  • Okazaki Y; Engineering Research Center for Biorenewable Chemicals, Iowa State University, Ames, Iowa 50011.
  • Zhang R; Metabolomics Research Group, RIKEN Center for Sustainable Resource Science, Yokohama 230-0045, Japan.
  • Saito K; Engineering Research Center for Biorenewable Chemicals, Iowa State University, Ames, Iowa 50011.
  • Nikolau BJ; Department of Chemical Engineering, University of Southern California, Los Angeles, California 90007.
Plant Physiol ; 183(2): 517-529, 2020 06.
Article en En | MEDLINE | ID: mdl-32245791
Plant fatty acid biosynthesis occurs in both plastids and mitochondria. Here, we report the identification and characterization of Arabidopsis (Arabidopsis thaliana) genes encoding three enzymes shared between the mitochondria- and plastid-localized type II fatty acid synthase systems (mtFAS and ptFAS, respectively). Two of these enzymes, ß-ketoacyl-acyl carrier protein (ACP) reductase and enoyl-ACP reductase, catalyze two of the reactions that constitute the core four-reaction cycle of the FAS system, which iteratively elongates the acyl chain by two carbon atoms per cycle. The third enzyme, malonyl-coenzyme A:ACP transacylase, catalyzes the reaction that loads the mtFAS system with substrate by malonylating the phosphopantetheinyl cofactor of ACP. GFP fusion experiments revealed that the these enzymes localize to both chloroplasts and mitochondria. This localization was validated by characterization of mutant alleles, which were rescued by transgenes expressing enzyme variants that were retargeted only to plastids or only to mitochondria. The singular retargeting of these proteins to plastids rescued the embryo lethality associated with disruption of the essential ptFAS system, but these rescued plants displayed phenotypes typical of the lack of mtFAS function, including reduced lipoylation of the H subunit of the glycine decarboxylase complex, hyperaccumulation of glycine, and reduced growth. However, these latter traits were reversible in an elevated-CO2 atmosphere, which suppresses mtFAS-associated photorespiration-dependent chemotypes. Sharing enzymatic components between mtFAS and ptFAS systems constrains the evolution of these nonredundant fatty acid biosynthetic machineries.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arabidopsis / Ácido Graso Sintasas / Mitocondrias Idioma: En Revista: Plant Physiol Año: 2020 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arabidopsis / Ácido Graso Sintasas / Mitocondrias Idioma: En Revista: Plant Physiol Año: 2020 Tipo del documento: Article Pais de publicación: Estados Unidos