Your browser doesn't support javascript.
loading
4D imaging of lithium-batteries using correlative neutron and X-ray tomography with a virtual unrolling technique.
Ziesche, Ralf F; Arlt, Tobias; Finegan, Donal P; Heenan, Thomas M M; Tengattini, Alessandro; Baum, Daniel; Kardjilov, Nikolay; Markötter, Henning; Manke, Ingo; Kockelmann, Winfried; Brett, Dan J L; Shearing, Paul R.
Afiliación
  • Ziesche RF; Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London, WC1E 7JE, UK.
  • Arlt T; STFC, Rutherford Appleton Laboratory, ISIS Facility, Harwell, OX11 0QX, UK.
  • Finegan DP; Technische Universität Berlin, Strasse des 17. Juni 135, 10624, Berlin, Germany.
  • Heenan TMM; National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, CO, 80401, USA.
  • Tengattini A; Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London, WC1E 7JE, UK.
  • Baum D; The Faraday Institution, Quad One, Harwell Science and Innovation Campus, Didcot, OX11 0RA, UK.
  • Kardjilov N; Grenoble INP, CNRS, 3SR, Univ. Grenoble Alpes, 38000, Grenoble, France.
  • Markötter H; Institut Laue-Langevin (ILL), 71 Avenue des Martyrs, 38000, Grenoble, France.
  • Manke I; Zuse Institute Berlin, Takustraße 7, 14195, Berlin, Germany.
  • Kockelmann W; Helmholtz-Zentrum Berlin für Materialien und Energie (HZB), Hahn-Meitner-Platz 1, 14109, Berlin, Germany.
  • Brett DJL; Technische Universität Berlin, Strasse des 17. Juni 135, 10624, Berlin, Germany.
  • Shearing PR; Helmholtz-Zentrum Berlin für Materialien und Energie (HZB), Hahn-Meitner-Platz 1, 14109, Berlin, Germany.
Nat Commun ; 11(1): 777, 2020 02 07.
Article en En | MEDLINE | ID: mdl-32034126
The temporally and spatially resolved tracking of lithium intercalation and electrode degradation processes are crucial for detecting and understanding performance losses during the operation of lithium-batteries. Here, high-throughput X-ray computed tomography has enabled the identification of mechanical degradation processes in a commercial Li/MnO2 primary battery and the indirect tracking of lithium diffusion; furthermore, complementary neutron computed tomography has identified the direct lithium diffusion process and the electrode wetting by the electrolyte. Virtual electrode unrolling techniques provide a deeper view inside the electrode layers and are used to detect minor fluctuations which are difficult to observe using conventional three dimensional rendering tools. Moreover, the 'unrolling' provides a platform for correlating multi-modal image data which is expected to find wider application in battery science and engineering to study diverse effects e.g. electrode degradation or lithium diffusion blocking during battery cycling.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nat Commun Asunto de la revista: BIOLOGIA / CIENCIA Año: 2020 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nat Commun Asunto de la revista: BIOLOGIA / CIENCIA Año: 2020 Tipo del documento: Article Pais de publicación: Reino Unido