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Novel Elastically Stretchable Metal-Organic Framework Laden Hydrogel with Pearl-Net Microstructure and Freezing Resistance through Post-Synthetic Polymerization.
Xu, Jun; Wu, Congyi; Qiu, Yue; Tang, Xing; Zeng, Dawen.
Afiliación
  • Xu J; School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die Mould Technology, Huazhong University of Science and Technology (HUST), 1037 Luoyu Street, Wuhan, 430074, P. R. China.
  • Wu C; School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die Mould Technology, Huazhong University of Science and Technology (HUST), 1037 Luoyu Street, Wuhan, 430074, P. R. China.
  • Qiu Y; School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die Mould Technology, Huazhong University of Science and Technology (HUST), 1037 Luoyu Street, Wuhan, 430074, P. R. China.
  • Tang X; School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die Mould Technology, Huazhong University of Science and Technology (HUST), 1037 Luoyu Street, Wuhan, 430074, P. R. China.
  • Zeng D; School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die Mould Technology, Huazhong University of Science and Technology (HUST), 1037 Luoyu Street, Wuhan, 430074, P. R. China.
Macromol Rapid Commun ; 41(6): e1900573, 2020 Mar.
Article en En | MEDLINE | ID: mdl-32022971
Nanocomposite hydrogels (NCs) with mechanical properties suitable for a diverse range of applications can be made by combining polymer hydrogel networks with various inorganic nanoparticles. However, the mechanical properties and functions of conventional NCs are seriously limited by the poor structural or functional tunability of common nanofillers and by the low amounts of such fillers that can be added. Here, the fabrication of novel elastically stretchable and compressible nanocomposite hydrogels (MIL-101-MAAm/PAAm) with a distinctive pearl-net microstructure and a metal-organic framework (MOF) content in the range of 20-60 wt% through post-synthetic polymerization (PSP) is reported. The MOFs, which are compatible with polymers and have a high degree of modifiability in structure and functions, are used as nanofillers. Such MOF-laden hydrogels can withstand 500% tensile strain or 90% compressive strain without fracture and recover quickly upon unloading. They are also resistant to freezing at -25 °C. In addition, the problems associated with poor flexibility and processability of MOFs are overcome by the hybridization of hydrogel polymer matrices with MOFs. The results of this work not only provide a new perspective on preparing NCs but also indicate a promising path for applying MOFs in flexible devices.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Hidrogeles / Nanocompuestos / Nanopartículas / Estructuras Metalorgánicas Idioma: En Revista: Macromol Rapid Commun Año: 2020 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Hidrogeles / Nanocompuestos / Nanopartículas / Estructuras Metalorgánicas Idioma: En Revista: Macromol Rapid Commun Año: 2020 Tipo del documento: Article Pais de publicación: Alemania