Modular Synthesis of Carbon-Substituted Furoxans via Radical Addition Pathway. Useful Tool for Transformation of Aliphatic Carboxylic Acids Based on "Build-and-Scrap" Strategy.

Matsubara, Ryosuke; Kim, Hojin; Sakaguchi, Takaya; Xie, Weibin; Zhao, Xufeng; Nagoshi, Yuto; Wang, Chaoyu; Tateiwa, Masahiro; Ando, Akihiro; Hayashi, Masahiko; Yamanaka, Masahiro; Tsuneda, Takao

Matsubara, Ryosuke; Kim, Hojin; Sakaguchi, Takaya; Xie, Weibin; Zhao, Xufeng; Nagoshi, Yuto; Wang, Chaoyu; Tateiwa, Masahiro; Ando, Akihiro; Hayashi, Masahiko; Yamanaka, Masahiro; Tsuneda, Takao.

Afiliación

Matsubara R; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Kim H; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Sakaguchi T; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Xie W; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Zhao X; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Nagoshi Y; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Wang C; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Tateiwa M; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Ando A; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Hayashi M; Department of Chemistry, Graduate School of Science , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.
Yamanaka M; Department of Chemistry and Research Center for Smart Molecules , Rikkyo University , 3-34-1 Nishi-Ikebukuro , Toshima-ku, Tokyo 171-8501 , Japan.
Tsuneda T; Graduate School of Science, Technology and Innovation , Kobe University , Nada-ku, Kobe , Hyogo 657-8501 , Japan.

Org Lett ; 22(3): 1182-1187, 2020 02 07.

Article en En | MEDLINE | ID: mdl-31976676

RESUMEN

Utilizing radical chemistry, a new general C-C bond formation on the furoxan ring was developed. By taking advantage of the lability of furoxans, a wide variety of transformation of the synthesized furoxans have been demonstrated. Thus, this developed methodology enabled not only the modular synthesis of furoxans but also short-step transformations of carboxylic acids to a broad range of functional groups.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos

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