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BaP6 N10 NH:Eu2+ as a Case Study-An Imidonitridophosphate Showing Luminescence.
Wendl, Sebastian; Eisenburger, Lucien; Zipkat, Mirjam; Günther, Daniel; Wright, Jonathan P; Schmidt, Peter J; Oeckler, Oliver; Schnick, Wolfgang.
Afiliación
  • Wendl S; Department of Chemistry, Ludwig Maximilians University Munich, Butenandtstr. 5-13, 81377, München, Germany.
  • Eisenburger L; Department of Chemistry, Ludwig Maximilians University Munich, Butenandtstr. 5-13, 81377, München, Germany.
  • Zipkat M; Institute for Mineralogy, Crystallography and Materials Science, Leipzig University, Scharnhorststr. 20, 04275, Leipzig, Germany.
  • Günther D; Department of Chemistry, Ludwig Maximilians University Munich, Butenandtstr. 5-13, 81377, München, Germany.
  • Wright JP; Institute for Mineralogy, Crystallography and Materials Science, Leipzig University, Scharnhorststr. 20, 04275, Leipzig, Germany.
  • Schmidt PJ; ESRF-The European Synchrotron, 71 avenue des Martyrs, 38000, Grenoble, France.
  • Oeckler O; Lumileds Phosphor Center Aachen (LPCA), Lumileds (Germany) GmbH, Philipsstr- 8, 52068, Aachen, Germany.
  • Schnick W; Institute for Mineralogy, Crystallography and Materials Science, Leipzig University, Scharnhorststr. 20, 04275, Leipzig, Germany.
Chemistry ; 26(22): 5010-5016, 2020 Apr 16.
Article en En | MEDLINE | ID: mdl-31944443
Barium imidonitridophosphate BaP6 N10 NH was synthesized at 5 GPa and 1000 °C with a high-pressure high-temperature approach using the multianvil technique. Ba(N3 )2 , P3 N5 and NH4 Cl were used as starting materials, applying a combination of azide and mineralizer routes. The structure elucidation of BaP6 N10 NH (P63 , a=7.5633(11), c=8.512(2) Å, Z=2) was performed by a combination of transmission electron microscopy and single-crystal diffraction with microfocused synchrotron radiation. Phase purity was verified by Rietveld refinement. 1 H and 31 P solid-state NMR and FTIR spectroscopy are consistent with the structure model. The chemical composition was confirmed by energy-dispersive X-ray spectroscopy and CHNS analyses. Eu2+ -doped samples of BaP6 N10 NH show blue emission upon excitation with UV to blue light (λem =460 nm, fwhm=2423 cm-1 ) representing unprecedented Eu2+ -luminescence of an imidonitride.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania