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Modification by transferrin increases the efficiency of delivery and the photodynamic effect of the quantum dot-phthalocyanine complex on A431 cells.
Gvozdev, D A; Ramonova, А А; Slonimskiy, Y B; Maksimov, Е G; Moisenovich, М М; Paschenko, V Z.
Afiliación
  • Gvozdev DA; Department of Biophysics, M.V. Lomonosov Moscow State University, 119992, Moscow, Russia. Electronic address: danil131054@mail.ru.
  • Ramonova АА; Bioengineering Department, M.V. Lomonosov Moscow State University, 119992, Moscow, Russia.
  • Slonimskiy YB; Bach Institute of Biochemistry, Federal Research Center of Biotechnology of the Russian Academy of Sciences, Moscow, Russia.
  • Maksimov ЕG; Department of Biophysics, M.V. Lomonosov Moscow State University, 119992, Moscow, Russia.
  • Moisenovich ММ; Bioengineering Department, M.V. Lomonosov Moscow State University, 119992, Moscow, Russia.
  • Paschenko VZ; Department of Biophysics, M.V. Lomonosov Moscow State University, 119992, Moscow, Russia.
Arch Biochem Biophys ; 678: 108192, 2019 12 15.
Article en En | MEDLINE | ID: mdl-31733214
Hybrid complexes of fluorescent nanoparticles and tetrapyrrole dyes are currently considered as promising third-generation photosensitizers for photodynamic therapy, including cancer treatment. Using nanoparticles as a platform for delivery of photosensitizers to target cells can increase the efficiency of photodynamic action. In this work, we synthesized a complex of polymer-coated CdSe/ZnS quantum dots, substituted phthalocyanines and human transferrin. Such complexes effectively enter human epidermoid carcinoma cells (A431) due to transferrin-mediated endocytosis and are localized in the perinuclear compartment. We observed an efficient excitation energy transfer from the quantum dot to phthalocyanine in the cells, which indicates stability of the complex upon its internalization. It was shown that the photodynamic activity of hybrid complexes covalently bonded to transferrin is 15% higher than the activity of unmodified hybrid complexes. Our results confirm the feasibility of using fluorescent nanoparticles to enhance the photodynamic properties of photosensitizers based on tetrapyrrole dyes.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fotoquimioterapia / Transferrina / Puntos Cuánticos / Indoles Aspecto: Implementation_research Límite: Humans Idioma: En Revista: Arch Biochem Biophys Año: 2019 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fotoquimioterapia / Transferrina / Puntos Cuánticos / Indoles Aspecto: Implementation_research Límite: Humans Idioma: En Revista: Arch Biochem Biophys Año: 2019 Tipo del documento: Article Pais de publicación: Estados Unidos