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PLX038: a PEGylated prodrug of SN-38 independent of UGT1A1 activity.
Fontaine, Shaun D; Santi, Angelo D; Reid, Ralph; Smith, Philip C; Ashley, Gary W; Santi, Daniel V.
Afiliación
  • Fontaine SD; ProLynx, 455 Mission Bay Blvd. South, Suite 341, San Francisco, CA, 94158, USA.
  • Santi AD; ProLynx, 455 Mission Bay Blvd. South, Suite 341, San Francisco, CA, 94158, USA.
  • Reid R; ProLynx, 455 Mission Bay Blvd. South, Suite 341, San Francisco, CA, 94158, USA.
  • Smith PC; Eshelman School of Pharmacy, University of North Carolina at Chapel Hill, Chapel Hill, NC, USA.
  • Ashley GW; ProLynx, 455 Mission Bay Blvd. South, Suite 341, San Francisco, CA, 94158, USA.
  • Santi DV; ProLynx, 455 Mission Bay Blvd. South, Suite 341, San Francisco, CA, 94158, USA. daniel.v.santi@prolynxllc.com.
Cancer Chemother Pharmacol ; 85(1): 225-229, 2020 01.
Article en En | MEDLINE | ID: mdl-31707444
PURPOSE: The purpose of this study was to determine the importance of UGT1A1 activity on the metabolism and pharmacokinetics of a releasable PEG ~ SN-38 conjugate, PLX038A. Irinotecan (CPT-11) is converted to the topoisomerase 1 inhibitor SN-38 by first-pass hepatic metabolism and is converted to its glucuronide SN-38G by UGT1A1. With diminished UGT1A1 activity, the high liver exposure to SN-38 can cause increased toxicity of CPT-11. In contrast, releasable PEG ~ SN-38 conjugates-such as PLX038-release SN-38 in the vascular compartment, and only low levels of SN-38 are expected to enter the liver by transport through the OATP1B1 transporter. METHODS: We measured CPT-11 and PLX038A metabolites in plasma and bile, and determined pharmacokinetics of PLX038A in UGT1A-deficient and replete rats. RESULTS: Compared to CPT-11, treatment of rats with PLX038A results in very low levels of biliary SN-38 and SN-38G, a low flux through UGT1A, and a low SN-38G/SN-38 ratio in plasma. Further, the pharmacokinetics of plasma PLX038A and SN-38 in rats deficient in UGT1A is unchanged compared to normal rats. CONCLUSIONS: The disposition of PEGylated SN-38 is independent of UGT1A activity in rats, and PLX038 may find utility in full-dose treatment of patients who are UGT1A1*28 homozygotes or have metastatic disease with coincidental or incidental liver dysfunction.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polietilenglicoles / Camptotecina / Profármacos / Regulación de la Expresión Génica / Glucuronosiltransferasa / Inhibidores de Topoisomerasa I / Irinotecán / Glucuronatos Límite: Animals Idioma: En Revista: Cancer Chemother Pharmacol Año: 2020 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polietilenglicoles / Camptotecina / Profármacos / Regulación de la Expresión Génica / Glucuronosiltransferasa / Inhibidores de Topoisomerasa I / Irinotecán / Glucuronatos Límite: Animals Idioma: En Revista: Cancer Chemother Pharmacol Año: 2020 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania