Your browser doesn't support javascript.
loading
Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7-Fold to 8-Fold Interpenetrated Metal-Organic Frameworks (MOFs).
Chen, Zhihui; Gallo, Gianpiero; Sawant, Vaishali A; Zhang, Tianxiang; Zhu, Menglong; Liang, Liangliang; Chanthapally, Anjana; Bolla, Geetha; Quah, Hong Sheng; Liu, Xiaogang; Loh, Kian Ping; Dinnebier, Robert E; Xu, Qing-Hua; Vittal, Jagadese J.
Afiliación
  • Chen Z; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Gallo G; Max-Planck-Institute for Solid State Research, Heisenbergstrasse 1, Stuttgart, 70569, Germany.
  • Sawant VA; Department of Chemistry and Biology "A. Zambelli", University of Salerno, Via Giovanni Paolo II, 132, Fisciano (SA), 84084, Italy.
  • Zhang T; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Zhu M; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Liang L; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Chanthapally A; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Bolla G; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Quah HS; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Liu X; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Loh KP; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Dinnebier RE; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
  • Xu QH; Max-Planck-Institute for Solid State Research, Heisenbergstrasse 1, Stuttgart, 70569, Germany.
  • Vittal JJ; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
Angew Chem Int Ed Engl ; 59(2): 833-838, 2020 Jan 07.
Article en En | MEDLINE | ID: mdl-31573739
Interpenetration in metal-organic frameworks (MOFs) is an intriguing phenomenon with significant impacts on their properties, and functional applications. Herein, we show that a 7-fold interpenetrated MOF (1) is transformed into an 8-fold interpenetrated MOF by the loss of DMF in a single-crystal-to-single-crystal manner. This is accompanied by a giant enhancement of the second harmonic generation (SHG ca. 125 times) and two-photon photoluminescence (ca. 14 times). The strengthened π-π interaction between the individual diamondoid networks and intensified oscillator strength of the molecules aid the augment of dipole moments and boost the nonlinear optical conversion efficiency. Large positive and negative thermal expansions of 1 occur at 30-150 °C before the loss of DMF. These results offer an avenue to manipulate the NLO properties of MOFs using interpenetration and provide access to tunable single-crystal NLO devices.
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2020 Tipo del documento: Article País de afiliación: Singapur Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2020 Tipo del documento: Article País de afiliación: Singapur Pais de publicación: Alemania