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An Americium-Containing Metal-Organic Framework: A Platform for Studying Transplutonium Elements.
Ridenour, J August; Surbella, Robert G; Gelis, Artem V; Koury, Daniel; Poineau, Frederic; Czerwinski, Kenneth R; Cahill, Christopher L.
Afiliación
  • Ridenour JA; Department of Chemistry, The George Washington University, 800 22nd St, NW, Washington D.C., 20052, USA.
  • Surbella RG; Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA, 99354, USA.
  • Gelis AV; Radiochemistry, Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Pkwy, Las Vegas, NV, 89154, USA.
  • Koury D; Radiochemistry, Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Pkwy, Las Vegas, NV, 89154, USA.
  • Poineau F; Radiochemistry, Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Pkwy, Las Vegas, NV, 89154, USA.
  • Czerwinski KR; Radiochemistry, Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Pkwy, Las Vegas, NV, 89154, USA.
  • Cahill CL; Department of Chemistry, The George Washington University, 800 22nd St, NW, Washington D.C., 20052, USA.
Angew Chem Int Ed Engl ; 58(46): 16508-16511, 2019 Nov 11.
Article en En | MEDLINE | ID: mdl-31536176
The synthesis, structure, and spectroscopic characterization of the first transplutonium metal-organic framework (MOF) is described. The preparation and structure of Am-GWMOF-6, [Am2 (C6 H8 O4 )3 (H2 O)2 ][(C10 H8 N2 )], is analogous to that of the isostructural trivalent lanthanide-only containing material GWMOF-6. The presented MOF architecture is used as a platform to probe Am3+ coordination chemistry and guest-enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self-irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania