Niobium isocyanide complexes, Nb(CNAr)<sub>6</sub>, with Ar = 2,6-dimethylphenyl (Xyl), a diamagnetic dimer containing four reductively coupled isocyanides, and Ar = 2,6-diisopropylphenyl (Dipp), a paramagnetic monomer analogous to the highly unstable hexacarbonylniobium(0).

Kucera, Benjamin E; Roberts, Christopher J; Young, Victor G; Brennessel, William W; Ellis, John E

Niobium isocyanide complexes, Nb(CNAr)₆, with Ar = 2,6-dimethylphenyl (Xyl), a diamagnetic dimer containing four reductively coupled isocyanides, and Ar = 2,6-diisopropylphenyl (Dipp), a paramagnetic monomer analogous to the highly unstable hexacarbonylniobium(0).

Kucera, Benjamin E; Roberts, Christopher J; Young, Victor G; Brennessel, William W; Ellis, John E.

Afiliación

Kucera BE; Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA.
Roberts CJ; Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA.
Young VG; Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA.
Brennessel WW; Department of Chemistry, University of Rochester, Rochester, NY 14620, USA.
Ellis JE; Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA.

Acta Crystallogr C Struct Chem ; 75(Pt 9): 1259-1265, 2019 09 01.

Article en En | MEDLINE | ID: mdl-31484814

Palabras clave

2,6-diisopropylphenyl isocyanide; 2,6-dimethylphenyl isocyanide; crystal structure; isocyanide; low-valent; niobium; squaramidinate; squarate

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Struct Chem Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

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