Synthesis of Multifunctional Aryl(trifloxyalkenyl)iodonium Triflate Salts.

Tóth, Balázs L; Béke, Ferenc; Egyed, Orsolya; Bényei, Attila; Stirling, András; Novák, Zoltán

Tóth, Balázs L; Béke, Ferenc; Egyed, Orsolya; Bényei, Attila; Stirling, András; Novák, Zoltán.

Afiliación

Tóth BL; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
Béke F; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
Egyed O; Research Centre for Natural Sciences of the Hungarian Academy of Sciences, Magyar Tudósok körútja 2, H-1117 Budapest, Hungary.
Bényei A; Department of Pharmaceutical Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen, Hungary.
Stirling A; Research Centre for Natural Sciences of the Hungarian Academy of Sciences, Magyar Tudósok körútja 2, H-1117 Budapest, Hungary.
Novák Z; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.

ACS Omega ; 4(5): 9188-9197, 2019 May 31.

Article en En | MEDLINE | ID: mdl-31460007

RESUMEN

A convenient procedure for the synthesis of aryl(trifloxyalkenyl)iodonium triflate salts from commercially available (diacetoxyiodo)benzene, trimethylsilyl trifluoromethanesulfonate, and acetylenes under mild conditions was developed. The obtained multifunctional hypervalent vinyliodonium salts equipped with electrophilic and nucleophilic functions could serve as novel C2 synthons for organic transformations. The structure of the iodonium salts was identified by multidimensional NMR spectroscopy and X-ray crystallography.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Omega Año: 2019 Tipo del documento: Article País de afiliación: Hungria Pais de publicación: Estados Unidos

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