Rhodium(III)-Catalyzed Oxidative Allylic C-H Indolylation via Nucleophilic Cyclization.

Sun, Jiaqiong; Wang, Kuan; Wang, Peiyuan; Zheng, Guangfan; Li, Xingwei

Sun, Jiaqiong; Wang, Kuan; Wang, Peiyuan; Zheng, Guangfan; Li, Xingwei.

Afiliación

Sun J; Key Laboratory of Applied Surface and Colloid Chemistry of MOE & School of Chemistry and Chemical Engineering , Shaanxi Normal University (SNNU) , Xi'an 710062 , China.
Wang K; Key Laboratory of Applied Surface and Colloid Chemistry of MOE & School of Chemistry and Chemical Engineering , Shaanxi Normal University (SNNU) , Xi'an 710062 , China.
Wang P; Key Laboratory of Applied Surface and Colloid Chemistry of MOE & School of Chemistry and Chemical Engineering , Shaanxi Normal University (SNNU) , Xi'an 710062 , China.
Zheng G; Key Laboratory of Applied Surface and Colloid Chemistry of MOE & School of Chemistry and Chemical Engineering , Shaanxi Normal University (SNNU) , Xi'an 710062 , China.
Li X; Key Laboratory of Applied Surface and Colloid Chemistry of MOE & School of Chemistry and Chemical Engineering , Shaanxi Normal University (SNNU) , Xi'an 710062 , China.

Org Lett ; 21(12): 4662-4666, 2019 Jun 21.

Article en En | MEDLINE | ID: mdl-31184193

RESUMEN

Reported herein is a mild synthesis of 3-allylindoles via Rh(III)-catalyzed allylic C-H activation of olefins and coupling with o-alkynylanilines. The reaction proceeded via initial nucleophilic cyclization of o-alkynylanilines followed by oxidative coupling with allylic C-H bonds via an Î·3-allyl intermediate.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2019 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

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