Cation exchange reversibly switches rotor speed and is monitored by a networked fluorescent reporter.

Özer, Merve S; Paul, Indrajit; Goswami, Abir; Schmittel, Michael

Özer, Merve S; Paul, Indrajit; Goswami, Abir; Schmittel, Michael.

Afiliación

Özer MS; Center of Micro and Nanochemistry and Engineering, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany. schmittel@chemie.uni-siegen.de.

Dalton Trans ; 48(25): 9043-9047, 2019 Jun 25.

Article en En | MEDLINE | ID: mdl-31173016

RESUMEN

Framework 1, a freely rotating turnstile, is transformed by sequential metal ion addition into the coordination-based double-minimum rotors [M2(1)]2n+ that operate at 8 kHz (M = Zn2+; n = 2) and 30 kHz (M = Cu+; n = 1). In a network with the fluorescent receptor 2, the metal ion exchange at [M2(1)]2n+ and thus indirectly the rotor speed is reported by distinct fluorescence changes at 2.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Reino Unido

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