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Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations.
Jia, Fei; Hupatz, Henrik; Yang, Liu-Pan; Schröder, Hendrik V; Li, Dong-Hao; Xin, Shan; Lentz, Dieter; Witte, Felix; Xie, Xiaojiang; Paulus, Beate; Schalley, Christoph A; Jiang, Wei.
Afiliación
  • Jia F; Institut für Chemie und Biochemie , Freie Universität Berlin , Takustrasse 3 , 14195 Berlin , Germany.
  • Hupatz H; Department of Chemistry and Shenzhen Grubbs Institute , Southern University of Science and Technology , Xueyuan Boulevard 1088 , Shenzhen 518055 , China.
  • Yang LP; Institut für Chemie und Biochemie , Freie Universität Berlin , Takustrasse 3 , 14195 Berlin , Germany.
  • Schröder HV; Department of Chemistry and Shenzhen Grubbs Institute , Southern University of Science and Technology , Xueyuan Boulevard 1088 , Shenzhen 518055 , China.
  • Li DH; Institut für Chemie und Biochemie , Freie Universität Berlin , Takustrasse 3 , 14195 Berlin , Germany.
  • Xin S; Department of Chemistry and Shenzhen Grubbs Institute , Southern University of Science and Technology , Xueyuan Boulevard 1088 , Shenzhen 518055 , China.
  • Lentz D; Department of Chemistry and Shenzhen Grubbs Institute , Southern University of Science and Technology , Xueyuan Boulevard 1088 , Shenzhen 518055 , China.
  • Witte F; Institut für Chemie und Biochemie , Freie Universtät Berlin , Fabeckstrasse 34-36 , 14195 Berlin , Germany.
  • Xie X; Institut für Chemie und Biochemie , Freie Universität Berlin , Takustrasse 3 , 14195 Berlin , Germany.
  • Paulus B; Department of Chemistry and Shenzhen Grubbs Institute , Southern University of Science and Technology , Xueyuan Boulevard 1088 , Shenzhen 518055 , China.
  • Schalley CA; Institut für Chemie und Biochemie , Freie Universität Berlin , Takustrasse 3 , 14195 Berlin , Germany.
  • Jiang W; Institut für Chemie und Biochemie , Freie Universität Berlin , Takustrasse 3 , 14195 Berlin , Germany.
J Am Chem Soc ; 141(10): 4468-4473, 2019 03 13.
Article en En | MEDLINE | ID: mdl-30785740
We report a quite flexible naphthol-based cage (so-called "naphthocage") which adopts a self-inclusion conformation in its free state and is able to bind singly charged organic cations extremely strongly ( Ka > 107 M-1). Ion-selective electrodes prepared with this naphthocage show a super-Nernstian response to acetylcholine. In addition, the highly stable complex (1010 M-1) between ferrocenium and the naphthocage can be switched electrochemically, which lays a basis for its application in stimuli-responsive materials.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2019 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2019 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Estados Unidos