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One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn-Teller distortion correlated to π-conjugation and magnetic properties.
Kimura, Shun; Uchida, Hikaru; Kusamoto, Tetsuro; Nishihara, Hiroshi.
Afiliación
  • Kimura S; Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan. kusamoto@chem.s.u-tokyo.ac.jp nisihara@chem.s.u-tokyo.ac.jp.
  • Uchida H; Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan. kusamoto@chem.s.u-tokyo.ac.jp nisihara@chem.s.u-tokyo.ac.jp.
  • Kusamoto T; Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan. kusamoto@chem.s.u-tokyo.ac.jp nisihara@chem.s.u-tokyo.ac.jp.
  • Nishihara H; Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan. kusamoto@chem.s.u-tokyo.ac.jp nisihara@chem.s.u-tokyo.ac.jp.
Dalton Trans ; 48(21): 7090-7093, 2019 Jun 07.
Article en En | MEDLINE | ID: mdl-30681087
The one-dimensional coordination polymer composed of CuII and an organic radical bisPyTM displayed temperature dependent Jahn-Teller distortion, which is correlated to the π-conjugation mode at the ligand as well as the magnetic properties. The ferromangetic bisPyTM-CuII interaction was enhanced by the reorientation of the CuII dx2-y2 orbital at low temperature.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article Pais de publicación: Reino Unido