Atomically precise Au<sub>144</sub>(SR)<sub>60</sub> nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects.

Dainese, Tiziano; Agrachev, Mikhail; Antonello, Sabrina; Badocco, Denis; Black, David M; Fortunelli, Alessandro; Gascón, José A; Stener, Mauro; Venzo, Alfonso; Whetten, Robert L; Maran, Flavio

Atomically precise Au₁₄₄(SR)₆₀ nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects.

Dainese, Tiziano; Agrachev, Mikhail; Antonello, Sabrina; Badocco, Denis; Black, David M; Fortunelli, Alessandro; Gascón, José A; Stener, Mauro; Venzo, Alfonso; Whetten, Robert L; Maran, Flavio.

Afiliación

Dainese T; Department of Chemistry , University of Padova , via Marzolo 1 , 35131 Padova , Italy . Email: flavio.maran@unipd.it.
Agrachev M; Department of Chemistry , University of Padova , via Marzolo 1 , 35131 Padova , Italy . Email: flavio.maran@unipd.it.
Antonello S; Department of Chemistry , University of Padova , via Marzolo 1 , 35131 Padova , Italy . Email: flavio.maran@unipd.it.
Badocco D; Department of Chemistry , University of Padova , via Marzolo 1 , 35131 Padova , Italy . Email: flavio.maran@unipd.it.
Black DM; Department of Physics and Astronomy , University of Texas at San Antonio , One UTSA Circle , San Antonio , Texas 78249 , USA.
Fortunelli A; National Research Council , CNR-ICCOM , 56124 Pisa , Italy.
Gascón JA; Department of Chemistry , University of Connecticut , 55 North Eagleville Road , Storrs , 06269 Connecticut , USA.
Stener M; Department of Chemical and Pharmaceutical Sciences , University of Trieste , 34127 Trieste , Italy.
Venzo A; National Research Council , CNR-ICMATE , Department of Chemistry , University of Padova , via Marzolo 1 , 35131 Padova , Italy.
Whetten RL; Department of Physics and Astronomy , University of Texas at San Antonio , One UTSA Circle , San Antonio , Texas 78249 , USA.
Maran F; Department of Chemistry , University of Padova , via Marzolo 1 , 35131 Padova , Italy . Email: flavio.maran@unipd.it.

Chem Sci ; 9(47): 8796-8805, 2018 Dec 21.

Article en En | MEDLINE | ID: mdl-30647884

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Sci Año: 2018 Tipo del documento: Article Pais de publicación: Reino Unido

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