Alleviating Efficiency Roll-Off of Hybrid Single-Emitting Layer WOLED Utilizing Bipolar TADF Material as Host and Emitter.
ACS Appl Mater Interfaces
; 11(2): 2197-2204, 2019 Jan 16.
Article
en En
| MEDLINE
| ID: mdl-30565918
Hybrid single-emitting layer (SEML) white organic light-emitting diodes (WOLEDs) incorporating blue thermally activated delayed fluorescent (TADF) or fluorescent materials and yellow phosphors have been widely utilized for solid-state lighting. Nonetheless, developing appropriate host materials to reduce the large efficiency roll-off at high luminance is still an unsolved issue. Here, two TADF materials denoted as TRZ-CF and TRZ-CzF were synthesized, with electroluminescent emission peaking at 476 and 460 nm, respectively. In particular, TRZ-CF, using 7,7-dimethyl-5,7-dihydroindeno[2,1- b]carbazole (CF) as donor moiety, maintained both highly efficient blue emission (EQEmax = 20.0%) and excellent charge transport abilities. The WOLED utilizing TRZ-CF as host material, doped by 0.8 wt % iridium(III) bis(4-phenylthieno[3,2- c]pyridinato- N, C2') (PO-01), has EQEmax of 20.3%, realizing the lowest roll-off to date of less than 2% at a luminance of 10 000 cd/m2. The efficiency roll-off is alleviated through the reduction the exciton quenching and triplet-triplet annihilation (TTA) within the light-emitting layer, benefited from the TADF effect and bipolar property. The hybrid SEML WOLED exhibits Commission Internationale de L'Eclairage (CIE) coordinates of (0.38, 0.45), providing a practical way to simplify the production complexity and to reduce efficiency roll-off for solid-state lighting.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Asunto de la revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Año:
2019
Tipo del documento:
Article
Pais de publicación:
Estados Unidos