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3D Hierarchical Co-Al Layered Double Hydroxides with Long-Term Stabilities and High Rate Performances in Supercapacitors.
Zai, Jiantao; Liu, Yuanyuan; Li, Xiaomin; Ma, Zi-Feng; Qi, Rongrong; Qian, Xuefeng.
Afiliación
  • Zai J; Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240 People's Republic of China.
  • Liu Y; Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240 People's Republic of China.
  • Li X; Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240 People's Republic of China.
  • Ma ZF; Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240 People's Republic of China.
  • Qi R; Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240 People's Republic of China.
  • Qian X; Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240 People's Republic of China.
Nanomicro Lett ; 9(2): 21, 2017.
Article en En | MEDLINE | ID: mdl-30460317
Three-dimensional (3D) flower-like Co-Al layered double hydroxide (Co-Al-LDH) architectures composed of atomically thin nanosheets were successfully synthesized via a hydrothermal method in a mixed solvent of water and butyl alcohol. Owing to the unique hierarchical structure and modification by butyl alcohol, the electrochemical stability and the charge/mass transport of the Co-Al-LDHs was improved. When used in supercapacitors, the obtained Co-Al-LDHs deliver a high specific capacitance of 838 F g-1 at a current density of 1 A g-1 and excellent rate performance (753 F g-1 at 30 A g-1 and 677 F g-1 at 100 A g-1), as well as excellent cycling stability with 95% retention of the initial capacitance even after 20,000 cycles at a current density of 5 A g-1. This work provides a promising alternative strategy to enhance the electrochemical properties of supercapacitors.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomicro Lett Año: 2017 Tipo del documento: Article Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomicro Lett Año: 2017 Tipo del documento: Article Pais de publicación: Alemania