3D Hierarchical Co-Al Layered Double Hydroxides with Long-Term Stabilities and High Rate Performances in Supercapacitors.
Nanomicro Lett
; 9(2): 21, 2017.
Article
en En
| MEDLINE
| ID: mdl-30460317
Three-dimensional (3D) flower-like Co-Al layered double hydroxide (Co-Al-LDH) architectures composed of atomically thin nanosheets were successfully synthesized via a hydrothermal method in a mixed solvent of water and butyl alcohol. Owing to the unique hierarchical structure and modification by butyl alcohol, the electrochemical stability and the charge/mass transport of the Co-Al-LDHs was improved. When used in supercapacitors, the obtained Co-Al-LDHs deliver a high specific capacitance of 838 F g-1 at a current density of 1 A g-1 and excellent rate performance (753 F g-1 at 30 A g-1 and 677 F g-1 at 100 A g-1), as well as excellent cycling stability with 95% retention of the initial capacitance even after 20,000 cycles at a current density of 5 A g-1. This work provides a promising alternative strategy to enhance the electrochemical properties of supercapacitors.
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01-internacional
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MEDLINE
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En
Revista:
Nanomicro Lett
Año:
2017
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Article
Pais de publicación:
Alemania