Your browser doesn't support javascript.
loading
Wavelength-Controlled Dynamic Metathesis: A Light-Driven Exchange Reaction between Disulfide and Diselenide Bonds.
Fan, Fuqiang; Ji, Shaobo; Sun, Chenxing; Liu, Cheng; Yu, Ying; Fu, Yu; Xu, Huaping.
Afiliación
  • Fan F; Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Ji S; College of Sciences, Northeastern University, Shenyang, 110819, China.
  • Sun C; Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Liu C; Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Yu Y; Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Fu Y; Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Xu H; College of Sciences, Northeastern University, Shenyang, 110819, China.
Angew Chem Int Ed Engl ; 57(50): 16426-16430, 2018 Dec 10.
Article en En | MEDLINE | ID: mdl-30345597
Wavelength-controlled dynamic processes are mostly based on light-triggered isomerization or the cleavage/formation of molecular connections. Control over dynamic metathesis reactions by different light wavelengths, which would be useful in controllable dynamic chemistry, has rarely been studied. Taking advantage of the different bond energies of disulfide and diselenide bonds, we have developed a wavelength-driven exchange reaction between disulfides and diselenides, which underwent metathesis under UV light to produce Se-S bonds. When irradiated with visible light, the Se-S bonds were reversed back to those of the original reactants. The conversion of the exchange depends on the wavelength of the incident light. This light-driven metathesis chemistry was also applied to tune the mechanical properties of polymer materials. The visible-light-induced reverse reaction was compatible with reductant-catalyzed disulfide/diselenide metathesis, and could be utilized to develop a dissipative system with light as the energy input.
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: China Pais de publicación: Alemania