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"On Water" Surface-initiated Polymerization of Hydrophobic Monomers.
Che, Yunjiao; Zhang, Tao; Du, Yunhao; Amin, Ihsan; Marschelke, Claudia; Jordan, Rainer.
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  • Che Y; Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069, Dresden, Germany.
  • Zhang T; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069, Dresden, Germany.
  • Du Y; Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069, Dresden, Germany.
  • Amin I; Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069, Dresden, Germany.
  • Marschelke C; Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069, Dresden, Germany.
  • Jordan R; Leibniz-Institut für Plasmaforschung und Technologie, Felix-Hausdorff-Straße 2, 17489, Greifswald, Germany.
Angew Chem Int Ed Engl ; 57(50): 16380-16384, 2018 Dec 10.
Article en En | MEDLINE | ID: mdl-30300921
We present the "on water" surface-initiated Cu-mediated controlled radical polymerization ("on water" SI-CuCRP) that converts hydrophobic monomers in aqueous reaction medium to polymer brushes at unparalleled speed and efficiency. The method allows the facile conversion of a variety of common monomers under most simple reaction conditions and with minimal monomer amounts to thick and homogeneous polymer brushes. The highly living character of the "on water" SI-CuCRP allowed the preparation of decablock (homo)polymer brushes and opens the pathway to sequentially controlled polymer brushes on solids.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania