Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone).
Soft Matter
; 14(39): 7945-7949, 2018 Oct 10.
Article
en En
| MEDLINE
| ID: mdl-30226247
We present an unexpected self-assembly of a glycoluril clip-poly(ε-caprolactone) conjugate in chloroform. The conjugate forms homodimer aggregates due to supramolecular interactions between glycoluril moieties, which was confirmed with MALDI-TOF-ms and 1H NMR. TEM revealed the formation of multilayered nanosized prism-shaped objects resembling tree bark in nature.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Soft Matter
Año:
2018
Tipo del documento:
Article
País de afiliación:
Polonia
Pais de publicación:
Reino Unido