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Preparation and Characterization of Macroalgae Biochar Nanomaterials with Highly Efficient Adsorption and Photodegradation Ability.
Zhou, Yarui; Zhang, Hailong; Cai, Lu; Guo, Jian; Wang, Yaning; Ji, Lili; Song, Wendong.
Afiliación
  • Zhou Y; College of Port and Transportation Engineering, Zhejiang Ocean University, Zhoushan 316022, China. zyr0612Z@gmail.com.
  • Zhang H; Institute of Innovation & Application, Zhejiang Ocean University, Zhoushan 316022, China. zhanghailong@zjou.edu.cn.
  • Cai L; College of Environmental and Science Technology, Donghua University, Shanghai 201620, China. cailu@zjou.edu.cn.
  • Guo J; College of Food and Medical, Zhejiang Ocean University, Zhoushan 316022, China. guojian@zjou.edu.cn.
  • Wang Y; Institute of Innovation & Application, Zhejiang Ocean University, Zhoushan 316022, China. wangyaning@zjou.edu.cn.
  • Ji L; Institute of Innovation & Application, Zhejiang Ocean University, Zhoushan 316022, China. jilili@zjou.edu.cn.
  • Song W; College of Petrochemical and Energy Engineering, Zhejiang Ocean University, Zhoushan 316022, China. songwendong@zjou.edu.cn.
Materials (Basel) ; 11(9)2018 Sep 13.
Article en En | MEDLINE | ID: mdl-30217033
In this study, carbonized kelp biochar (AKB) modified by KOH impregnation and photocatalytic Bi2MoO6/AKB composite (BKBC) nanomaterials were the first time successfully synthesized for efficient removal of dyes in aqueous solution. BET, XRD, FT-IR, and SEM were employed to characterize as-prepared samples. UV-vis and other test results indicated that the removal efficiency of methylene blue (MB) was 61.39% and 94.12% for BKBC and AKB, respectively, which was up to 13 times and 20 times higher in comparison with pure Bi2MoO6 (PBM). In addition, the equilibrium adsorption capacity of MB could reach up to 324.1 mg/g for AKB. This high dyes adsorption performance could be likely attributed to its high specific surface area (507.177 m²/g) and its abundant presence of various functional groups such as ⁻OH and =C⁻H on AKB. Particularly, the existing of amorphous carbon and transition metal oxides, such as Fe2O3 and Mn5O8, could be beneficial for the photodegradation of MB for AKB. Meanwhile, experimental data indicated that adsorption kinetics complied with the pseudo-second order model well, and all of the tests had satisfactory results in terms of the highly efficient adsorption and photodegradation activity of AKB nanomaterials, which suggested its great potential in wastewater treatment.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Materials (Basel) Año: 2018 Tipo del documento: Article País de afiliación: China Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Materials (Basel) Año: 2018 Tipo del documento: Article País de afiliación: China Pais de publicación: Suiza