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Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives.
Han, Jiao-Na; Du, Cong; Zhu, Xinju; Wang, Zheng-Long; Zhu, Yue; Chu, Zhao-Yang; Niu, Jun-Long; Song, Mao-Ping.
Afiliación
  • Han JN; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Du C; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Zhu X; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Wang ZL; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Zhu Y; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Chu ZY; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Niu JL; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
  • Song MP; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
Beilstein J Org Chem ; 14: 2090-2097, 2018.
Article en En | MEDLINE | ID: mdl-30202462
A cobalt-catalyzed C(sp2)-H alkoxylation of 1-naphthylamine derivatives has been disclosed, which represents an efficient approach to synthesize aryl ethers with broad functional group tolerance. It is noteworthy that secondary alcohols, such as hexafluoroisopropanol, isopropanol, isobutanol, and isopentanol, were well tolerated under the current catalytic system. Moreover, a series of biologically relevant fluorine-aryl ethers were easily obtained under mild reaction conditions after the removal of the directing group.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2018 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2018 Tipo del documento: Article Pais de publicación: Alemania