Unique Stereoselective Homolytic C-O Bond Activation in Diketopiperazine-Derived Alkoxyamines by Adjacent Amide Pyramidalization.

Amatov, Tynchtyk; Jangra, Harish; Pohl, Radek; Cisarová, Ivana; Zipse, Hendrik; Jahn, Ullrich

Amatov, Tynchtyk; Jangra, Harish; Pohl, Radek; Cisarová, Ivana; Zipse, Hendrik; Jahn, Ullrich.

Afiliación

Amatov T; Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo námestí 2, 16610, Prague, Czech Republic.
Jangra H; Ludwig Maximilian University, Department of Chemistry, Butenandstrasse 5-13, 81377, München, Germany.
Pohl R; Ludwig Maximilian University, Department of Chemistry, Butenandstrasse 5-13, 81377, München, Germany.
Cisarová I; Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo námestí 2, 16610, Prague, Czech Republic.
Zipse H; Department of Inorganic Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030/8, 12843, Prague, Czech Republic.
Jahn U; Ludwig Maximilian University, Department of Chemistry, Butenandstrasse 5-13, 81377, München, Germany.

Chemistry ; 24(57): 15336-15345, 2018 Oct 12.

Article en En | MEDLINE | ID: mdl-30092124

Palabras clave

amides; cleavage reactions; isomerization; persistent radical effect; radicals

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: República Checa Pais de publicación: Alemania

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