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Assembly and Chiral Memory Effects of Dynamic Macroscopic Supramolecular Helices.
Yuan, Tianyu; Sun, Zhimin; Mu, Anthony U; Zeng, Minxiang; Kalin, Alexander J; Cheng, Zhengdong; Olson, Mark A; Fang, Lei.
Afiliación
  • Yuan T; Health Science Platform, School of Pharmaceutical Science and Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.
  • Sun Z; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, Texas, 77843, USA.
  • Mu AU; Department of Materials Science and Engineering, Texas A&M University, 3003 TAMU, College Station, Texas, 77843, USA.
  • Zeng M; Health Science Platform, School of Pharmaceutical Science and Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin, 300072, P. R. China.
  • Kalin AJ; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, Texas, 77843, USA.
  • Cheng Z; Artie McFerrin Department of Chemical Engineering, Texas A&M University, 100 Spence Street, College Station, Texas, 77843, USA.
  • Olson MA; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, Texas, 77843, USA.
  • Fang L; Artie McFerrin Department of Chemical Engineering, Texas A&M University, 100 Spence Street, College Station, Texas, 77843, USA.
Chemistry ; 24(62): 16553-16557, 2018 Nov 07.
Article en En | MEDLINE | ID: mdl-30089198
Macroscopic enantiomerically pure helical supramolecular fibers are bottom-up assembled in aqueous media from a chiral π-electron donor template and an achiral π-electron acceptor. The helices can be assembled to the sub-millimeter scale with controlled handedness. These dynamic supramolecular architectures allow for a quantitative exchange of the chiral donor template with achiral analogues. During this process, a chiral memory effect was observed, affording enantiomerically pure helices composed entirely of achiral components.
Palabras clave

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article Pais de publicación: Alemania