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A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks.
Adonin, Sergey A; Udalova, Liubov I; Abramov, Pavel A; Novikov, Alexander S; Yushina, Irina V; Korolkov, Ilya V; Semitut, Evgeniy Y; Derzhavskaya, Tatiyana A; Stevenson, Keith J; Troshin, Pavel A; Sokolov, Maxim N; Fedin, Vladimir P.
Afiliación
  • Adonin SA; Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
  • Udalova LI; Novosibirsk State University, Pirogova St. 2, 630090, Novosibirsk, Russia.
  • Abramov PA; Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
  • Novikov AS; Novosibirsk State University, Pirogova St. 2, 630090, Novosibirsk, Russia.
  • Yushina IV; Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
  • Korolkov IV; Novosibirsk State University, Pirogova St. 2, 630090, Novosibirsk, Russia.
  • Semitut EY; Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7-9, 199034, Saint Petersburg, Russia.
  • Derzhavskaya TA; Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
  • Stevenson KJ; Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
  • Troshin PA; Novosibirsk State University, Pirogova St. 2, 630090, Novosibirsk, Russia.
  • Sokolov MN; Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
  • Fedin VP; Institute for Problems of Chemical Physics RAS, Semenov ave. 1, 142432, Chernogolovka, Russia.
Chemistry ; 24(55): 14707-14711, 2018 Oct 01.
Article en En | MEDLINE | ID: mdl-30020549
In the presence of different cations, reactions of [SbBr6 ]3- and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix }n- polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6-6.9 kcal mol-1 . Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: Rusia Pais de publicación: Alemania
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: Rusia Pais de publicación: Alemania