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Surface functionalisation significantly changes the physical and electronic properties of carbon nano-dots.
Swift, Thomas A; Duchi, Marta; Hill, Stephen A; Benito-Alifonso, David; Harniman, Robert L; Sheikh, Sadiyah; Davis, Sean A; Seddon, Annela M; Whitney, Heather M; Galan, M Carmen; Oliver, Thomas A A.
Afiliación
  • Swift TA; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk and School of Biological Sciences, Life Sciences Building, Tyndall Avenue, University of Bristol, BS8 1TH, UK and Bristol Centre for Functional Nanomaterials, HH Wills Physics L
  • Duchi M; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk.
  • Hill SA; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk.
  • Benito-Alifonso D; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk.
  • Harniman RL; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk.
  • Sheikh S; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk and Bristol Centre for Functional Nanomaterials, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK.
  • Davis SA; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk and Bristol Centre for Functional Nanomaterials, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK.
  • Seddon AM; Bristol Centre for Functional Nanomaterials, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK and School of Physics, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK.
  • Whitney HM; School of Biological Sciences, Life Sciences Building, Tyndall Avenue, University of Bristol, BS8 1TH, UK and Bristol Centre for Functional Nanomaterials, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK.
  • Galan MC; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk and Bristol Centre for Functional Nanomaterials, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK.
  • Oliver TAA; School of Chemistry, Cantock's Close, University of Bristol, BS8 1TS, UK. tom.oliver@bristol.ac.uk m.c.galan@bristol.ac.uk and Bristol Centre for Functional Nanomaterials, HH Wills Physics Laboratory, Tyndall Avenue, University of Bristol, BS8 1TL, UK.
Nanoscale ; 10(29): 13908-13912, 2018 Aug 07.
Article en En | MEDLINE | ID: mdl-29999508
Biomolecule functionalisation of carbon nano-dots (CDs) greatly enhances their biocompatibility and applicability, however, little is known about their molecular structure. Using an arsenal of spectroscopic and analytical techniques, we provide new insights into the physical and electronic structure of uncoated and glycan-functionalised CDs. Our studies reveal that surface functionalisation does not always result in a homogenous corona surrounding the core, and the choice of carbohydrate significantly affects the electronic structure of the surface CD states. Further, the average surface coverage of an ensemble of CDs can be probed via transient absorption spectroscopy. These findings have implications for CDs targeted at interactions with biological systems or local sensors.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanoscale Año: 2018 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanoscale Año: 2018 Tipo del documento: Article Pais de publicación: Reino Unido