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A functional genetic screen reveals sequence preferences within a key tertiary interaction in cobalamin riboswitches required for ligand selectivity.
Polaski, Jacob T; Kletzien, Otto A; Drogalis, Lea K; Batey, Robert T.
Afiliación
  • Polaski JT; Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA.
  • Kletzien OA; Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA.
  • Drogalis LK; Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA.
  • Batey RT; Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA.
Nucleic Acids Res ; 46(17): 9094-9105, 2018 09 28.
Article en En | MEDLINE | ID: mdl-29945209
Riboswitches are structured mRNA sequences that regulate gene expression by directly binding intracellular metabolites. Generating the appropriate regulatory response requires the RNA rapidly and stably acquire higher-order structure to form the binding pocket, bind the appropriate effector molecule and undergo a structural transition to inform the expression machinery. These requirements place riboswitches under strong kinetic constraints, likely restricting the sequence space accessible by recurrent structural modules such as the kink turn and the T-loop. Class-II cobalamin riboswitches contain two T-loop modules: one directing global folding of the RNA and another buttressing the ligand binding pocket. While the T-loop module directing folding is highly conserved, the T-loop associated with binding is substantially less so, with no clear consensus sequence. To further understand the functional role of the binding-associated module, a functional genetic screen of a library of riboswitches with the T-loop and its interacting nucleotides was used to build an experimental phylogeny comprised of sequences that possess a wide range of cobalamin-dependent regulatory activity. Our results reveal conservation patterns of the T-loop and its interaction with the binding core that allow for rapid tertiary structure formation and demonstrate its importance for generating strong ligand-dependent repression of mRNA expression.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Vitamina B 12 / ARN Bacteriano / Análisis de Secuencia de ARN / Riboswitch / Conformación de Ácido Nucleico Idioma: En Revista: Nucleic Acids Res Año: 2018 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Vitamina B 12 / ARN Bacteriano / Análisis de Secuencia de ARN / Riboswitch / Conformación de Ácido Nucleico Idioma: En Revista: Nucleic Acids Res Año: 2018 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido