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Imaging DNA single-strand breaks generated by reactive oxygen species using a liquid crystal-based sensor.
Kim, Hyeong Jin; Jang, Chang-Hyun.
Afiliación
  • Kim HJ; Department of Chemistry, Gachon University, San 65, Bokjeong-Dong, Sujeong-Gu, Seongnam-City, Gyeonggi-Do, 461-701, South Korea.
  • Jang CH; Department of Chemistry, Gachon University, San 65, Bokjeong-Dong, Sujeong-Gu, Seongnam-City, Gyeonggi-Do, 461-701, South Korea. Electronic address: chjang4u@gachon.ac.kr.
Anal Biochem ; 556: 1-6, 2018 09 01.
Article en En | MEDLINE | ID: mdl-29920235
DNA single-strand breaks (SSBs) have attracted much interest since they are highly related to carcinogenesis and ageing. Herein, we report a new liquid crystal (LC)-based sensor for the detection of DNA SSBs generated by reactive oxygen species (ROS) created from the Fenton reaction. The adsorption of single-stranded DNA (ssDNA) onto the cationic surfactant-laden aqueous/LC interface interferes with the surfactant layer, inducing a planar orientation of the LCs. However, the DNA SSBs generated by the Fenton reaction-produced ROS result in a decrease of the electrostatic interactions between the ssDNA and cationic surfactant molecules, causing rearrangement of the surfactant layer and reorientation of the LCs back to a homeotropic alignment. The changes in orientation of the LCs caused by the DNA SSBs are simply converted and observed as a shift from a bright optical image of the LCs to a dark one under a polarized light microscope. With this simple LC-based approach, the DNA SSBs could be detected more effectively and rapidly without any complex instrumentation or intricate processes. Therefore, our research provides a novel strategy for the detection of DNA damage as well as better insight into the DNA-damaging process.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: ADN de Cadena Simple / Técnicas Biosensibles / Especies Reactivas de Oxígeno / Cristales Líquidos / Roturas del ADN de Cadena Simple Idioma: En Revista: Anal Biochem Año: 2018 Tipo del documento: Article País de afiliación: Corea del Sur Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: ADN de Cadena Simple / Técnicas Biosensibles / Especies Reactivas de Oxígeno / Cristales Líquidos / Roturas del ADN de Cadena Simple Idioma: En Revista: Anal Biochem Año: 2018 Tipo del documento: Article País de afiliación: Corea del Sur Pais de publicación: Estados Unidos