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Treatment of winery wastewater by anodic oxidation using BDD electrode.
Candia-Onfray, Christian; Espinoza, Nicole; Sabino da Silva, Evanimek B; Toledo-Neira, Carla; Espinoza, L Carolina; Santander, Rocío; García, Verónica; Salazar, Ricardo.
Afiliación
  • Candia-Onfray C; Departamento de Química de los Materiales, Laboratorio de Electroquímica MedioAmbiental, LEQMA, Chile.
  • Espinoza N; Departamento de Química de los Materiales, Laboratorio de Electroquímica MedioAmbiental, LEQMA, Chile.
  • Sabino da Silva EB; Departamento de Química de los Materiales, Laboratorio de Electroquímica MedioAmbiental, LEQMA, Chile.
  • Toledo-Neira C; Departamento de Química de los Materiales, Laboratorio de Electroquímica MedioAmbiental, LEQMA, Chile.
  • Espinoza LC; Departamento de Química de los Materiales, Laboratorio de Electroquímica MedioAmbiental, LEQMA, Chile.
  • Santander R; Laboratorio de Cinética y Fotoquímica, Departamento de Ciencias del Ambiente, Facultad de Química y Biología, Chile.
  • García V; Centro de Estudios en Ciencia y Tecnología de Alimentos (CECTA), Universidad de Santiago de Chile, USACH, Casilla 40, Correo 33, Santiago, Chile.
  • Salazar R; Departamento de Química de los Materiales, Laboratorio de Electroquímica MedioAmbiental, LEQMA, Chile. Electronic address: ricardo.salazar@usach.cl.
Chemosphere ; 206: 709-717, 2018 Sep.
Article en En | MEDLINE | ID: mdl-29783056
The effective removal of organics from winery wastewater was obtained in real residual effluents from the wine industry using anodic oxidation (AO). The effluent had an initial organic load of [COD]0 of 3490 mg L-1 equal to [TOC]0 of 1320 mg L-1. In addition, more than 40 organic compounds were identified by means of GC-MS. Different density currents as well as the addition of electrolytes were tested during electrolysis. The results show the decay of [COD]t by 63.6% when no support electrolyte was added, whereas almost total mineralization and disinfection was reached after adding of 50 mM of sodium sulfate and sodium chloride and applying higher density currents. The presence of sulfate and chloride in large concentration favors the production of oxidants such as hydroxyl radicals and active chlorine species that react with organics in solution. Moreover, the addition of a supporting electrolyte to industrial wastewater increases conductivity, reduces cell potential and therefore, decreases the energy consumption of the AO process.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Medicamentos Herbarios Chinos Idioma: En Revista: Chemosphere Año: 2018 Tipo del documento: Article País de afiliación: Chile Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Medicamentos Herbarios Chinos Idioma: En Revista: Chemosphere Año: 2018 Tipo del documento: Article País de afiliación: Chile Pais de publicación: Reino Unido