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Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes.
Latendresse, Trevor P; Vieru, Veacheslav; Wilkins, Branford O; Bhuvanesh, Nattamai S; Chibotaru, Liviu F; Nippe, Michael.
Afiliación
  • Latendresse TP; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX, 77843, USA.
  • Vieru V; Theory of Nanomaterials Group, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.
  • Wilkins BO; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX, 77843, USA.
  • Bhuvanesh NS; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX, 77843, USA.
  • Chibotaru LF; Theory of Nanomaterials Group, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.
  • Nippe M; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX, 77843, USA.
Angew Chem Int Ed Engl ; 57(27): 8164-8169, 2018 07 02.
Article en En | MEDLINE | ID: mdl-29734485
A rare example of an organometallic terbium single-ion magnet is reported. A Tb3+ -[1]ferrocenophane complex displays a larger barrier to magnetization reversal than its isostructural Dy3+ analogue, which is reminiscent of trends observed for lanthanide-bis-phthalocyanine complexes. Detailed ab initio calculations support the experimental observations and suggest a significantly larger ground-state stabilization for the non-Kramers ion Tb3+ in the Tb complex than for the Kramers-ion Dy3+ in the Dy complex.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania
Texto completo
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Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania